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Angelina Jolie and Brad Pitt

Her relationship with Brad Pitt was her most famous — Brangelina! — but mostly because they fell in love in 2004 on the set of Mr. & Mrs. Smith when he was still married to Jennifer Aniston. The tabloid darlings had a huge family (he adopted her two and they added four more) and waited years before getting married at their French estate in 2014. But all the Miraval rosé in the world couldn’t save their relationship, which ended with an explosive fight aboard a private plane that their eldest son, Maddox, had to bust up. Their parting of ways was messy — a battle over their kids — and they’ve yet to agree to a divorce settlement.

(Photo: Tony Barson/WireImage)

3 weddings and a ... blood vial? Angelina Jolie's eventful romantic history

Suzy Byrne
Editor, Yahoo Entertainment

Blood vials! Cheating scandals! Angelina Jolie’s relationships have never been dull. With Entertainment Tonight reporting that the mom of six is dating again — amid her lengthy divorce from Brad Pitt — we look back at her romantic history, which has included married men, at least one (single) woman, and often a whole lotta drama.